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Nitrogen trichloride

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Nitrogen trichloride
Structural formula of nitrogen trichloride
Space-filling model of nitrogen trichloride
  Nitrogen, N
  Chlorine, Cl
Nitrogen trichloride
Names
Other names
Trichloramine
Agene
Nitrogen(III) chloride
Trichloroazane
Trichlorine nitride
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.030.029 Edit this at Wikidata
EC Number
  • 233-045-1
1840
RTECS number
  • QW974000
UNII
  • InChI=1S/Cl3N/c1-4(2)3 checkY
    Key: QEHKBHWEUPXBCW-UHFFFAOYSA-N checkY
  • InChI=1/Cl3N/c1-4(2)3
    Key: QEHKBHWEUPXBCW-UHFFFAOYAZ
  • ClN(Cl)Cl
Properties
NCl3
Molar mass 120.36 g·mol−1
Appearance yellow oily liquid
Odor chlorine-like
Density 1.653 g/mL
Melting point −40 °C (−40 °F; 233 K)
Boiling point 71 °C (160 °F; 344 K)
immiscible
slowly decomposes
Solubility soluble in benzene, chloroform, CCl4, CS2, PCl3
Structure
orthorhombic (below −40 °C)
trigonal pyramidal
0.6 D
Thermochemistry
232 kJ/mol
Hazards
NFPA 704 (fire diamond)
93 °C (199 °F; 366 K)
Related compounds
Other anions
Nitrogen trifluoride
Nitrogen tribromide
Nitrogen triiodide
Other cations
Phosphorus trichloride
Arsenic trichloride
Related chloramines
Monochloramine
Dichloramine
Related compounds
Nitrosyl chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Nitrogen trichloride, also known as trichloramine, is the chemical compound with the formula NCl3. This yellow, oily, and explosive liquid is most commonly encountered as a product of chemical reactions between ammonia-derivatives and chlorine (for example, in swimming pools). Alongside monochloramine and dichloramine, trichloramine is responsible for the distinctive 'chlorine smell' associated with swimming pools, where the compound is readily formed as a product from hypochlorous acid reacting with ammonia and other nitrogenous substances in the water, such as urea from urine.[1]

Preparation and occurrence

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The compound is generated by treatment of ammonium chloride with calcium hypochlorite. When prepared in an aqueous-dichloromethane mixture, the trichloramine is extracted into the nonaqueous phase.[2] Intermediates in this conversion include monochloramine and dichloramine, NH2Cl and NHCl2, respectively.

Nitrogen trichloride, trademarked as Agene, was at one time used to bleach flour,[3] but this practice was banned in the United States in 1949 due to safety concerns.

Structure and properties

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Like ammonia, NCl3 is a pyramidal molecule. The N-Cl distances are 1.76 Å, and the Cl-N-Cl angles are 107°.[4]

Nitrogen trichloride can form in small amounts when public water supplies are disinfected with monochloramine, and in swimming pools by disinfecting chlorine reacting with urea in urine and sweat from bathers.

Reactions and uses

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The chemistry of NCl3 has been well explored.[5] It is moderately polar with a dipole moment of 0.6 D. The nitrogen center is basic but much less so than ammonia. It is hydrolyzed by hot water to release ammonia and hypochlorous acid.

NCl3 + 3 H2O → NH3 + 3 HOCl

Concentrated samples of NCl3 can explode to give N2 and chlorine gas.

2 NCl3 → N2 + 3 Cl2

It react with some organic compounds to give amines.[2]


Safety

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Nitrogen trichloride can irritate mucous membranes—it is a lachrymatory agent, but has never been used as such.[6][7] The compound (rarely encountered) is a dangerous explosive, being sensitive to light, heat, even moderate shock, and organic compounds. Pierre Louis Dulong first prepared it in 1812, and lost several fingers and an eye in two explosions.[8] In 1813, an NCl3 explosion blinded Sir Humphry Davy temporarily, inducing him to hire Michael Faraday as a co-worker. They were both injured in another NCl3 explosion shortly thereafter.[9]

See also

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References

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  1. ^ "Chlorine Chemistry - Chlorine Compound of the Month: Chloramines: Understanding "Pool Smell"". American Chemistry Council. Retrieved 17 December 2019.
  2. ^ a b Kovacic, Peter; Chaudhary, Sohan S. (1968). "1-Amino-1-Methylcyclohexane". Organic Syntheses. 48: 4. doi:10.15227/orgsyn.048.0004.
  3. ^ Hawthorn, J.; Todd, J. P. (1955). "Some effects of oxygen on the mixing of bread doughs". Journal of the Science of Food and Agriculture. 6 (9): 501–511. Bibcode:1955JSFA....6..501H. doi:10.1002/jsfa.2740060906.
  4. ^ Holleman, A. F.; Wiberg, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 978-0-12-352651-9.
  5. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  6. ^ White, G. C. (1999). The Handbook of Chlorination and Alternative Disinfectants (4th ed.). Wiley. p. 322. ISBN 978-0-471-29207-4.
  7. ^ "Health Hazard Evaluation Report: Investigation of Employee Symptoms at an Indoor Water Park" (PDF). NIOSH ENews. 6 (4). August 2008. HETA 2007-0163-3062.
  8. ^ Thénard J. L.; Berthollet C. L. (1813). "Report on the work of Pierre Louis Dulong". Annales de Chimie et de Physique. 86 (6): 37–43.
  9. ^ Thomas, J.M. (1991). Michael Faraday and The Royal Institution: The Genius of Man and Place (PBK). CRC Press. p. 17. ISBN 978-0-7503-0145-9.

Further reading

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  • Jander, J. (1976). "Recent Chemistry and Structure Investigation of Nitrogen Triiodide, Tribromide, Trichloride, and Related Compounds". Advances in Inorganic Chemistry. Advances in Inorganic Chemistry and Radiochemistry. 19: 1–63. doi:10.1016/S0065-2792(08)60070-9. ISBN 9780120236190.
  • Kovacic, P.; Lowery, M. K.; Field, K. W. (1970). "Chemistry of N-Bromamines and N-Chloramines". Chemical Reviews. 70 (6): 639–665. doi:10.1021/cr60268a002.
  • Hartl, H.; Schöner, J.; Jander, J.; Schulz, H. (1975). "Die Struktur des Festen Stickstofftrichlorids (−125 °C)". Zeitschrift für Anorganische und Allgemeine Chemie. 413 (1): 61–71. doi:10.1002/zaac.19754130108.
  • Cazzoli, G.; Favero, P. G.; Dal Borgo, A. (1974). "Molecular Structure, Nuclear Quadrupole Coupling Constant and Dipole Moment of Nitrogen Trichloride from Microwave Spectroscopy". Journal of Molecular Spectroscopy. 50 (1–3): 82–89. Bibcode:1974JMoSp..50...82C. doi:10.1016/0022-2852(74)90219-7.
  • Bayersdorfer, L.; Engelhardt, U.; Fischer, J.; Höhne, K.; Jander, J. (1969). "Untersuchungen an Stickstoff–Chlor-Verbindungen. V. Infrarot- und RAMAN-Spektren von Stickstofftrichlorid". Zeitschrift für Anorganische und Allgemeine Chemie. 366 (3–4): 169–179. doi:10.1002/zaac.19693660308.
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